Yet another way to resolve a chlorine lock is to reach what is called breakpoint chlorination. Breakpoint chlorination is the point where the chemical bond that ties nitrogen, chlorine and ammonia together by using large amounts of chlorine. This will cause the chlorine residual to drop rapidly. Reaching a true chlorine breakpoint is vital to breaking a chlorine lock. If breakpoint is not reached using this method, the problem will only get worse. To accomplish a breakpoint, 7.6 free chlorine molecules are used to break apart an individual combined chlorine molecule. The amount of product you will need will vary depending on the type of shock you are using. Aside from knowing your total chlorine, free chlorine, number of gallons in the pool, and the weight of a gallon of water (8.34 lbs.), you will also need to know the type of pool shock you are using. Before attempting this method, the pH needs to be between 7.2-7.4. This equation will be a two part process. The first step will be determining the ppm of chlorine needed to reach breakpoint: (TC-FC) x 10. Using the same amount above, the equation would look like this: (5-3) x 10 = x ppm or 2 x 10 = 20 ppm. I will need 20 ppm of chlorine to reach breakpoint in this 15,000 gallon pool. The next step is to determine how much product I will need. I'm using calcium hypochlorite in this example and need 2 oz. per 10,000 for a 1 ppm increase. I'll need to multiply 2 oz. x (gallons in pool/10,000) x (ppm needed/ppm dosage) which simply put is: 2 oz. x (15,000/10,000) x (20 ppm/1 ppm) or 2 oz x 1.5 x 20= 60 oz. To convert ounces to pounds, I divide by 16: 60 oz./16= 3.75 lbs. So to reach breakpoint in my 15,000 gallon pool I will need 3.75 lbs. of calcium hypochlorite.